I'm just going on the available tools, not experience or documentation. You might want to test this with a partition (even just an image) you don't mind losing if it all goes wrong. Don't attempt this without taking a backup.
has a roll-back function to undo a conversion. I'm not sure if this works for partitions that weren't converted to btrfs-convert with btrfs.btrfs-convert
Start by unmounting the filesystem. If it's essential to the system, boot into a LiveCD.
Install btrfs-tools
sudo apt-get install btrfs-tools
Roll back the conversion
sudo btrfs-convert -r /dev/sdXn