Yes, latex paint can freeze and still be usable once it thaws out.
However, it is important to note that frozen paint will often separate into its different parts – the pigment (color) and binder (the part that keeps the pigment together).
If the paint color and consistency appear normal after thawing, then it should be all right to use.
To save frozen latex paint, it is important to allow it to slowly warm up to room temperature and stir it well.
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When you have to store latex paint during colder months, freezing can become an issue. This is particularly bad because as the water in the paint freezes, the whole substance can turn thick and grainy, making it completely unusable.
How to Save Frozen Latex Paint | DoItYourself.com
Freezing does ruin latex paint, but it can survive a few freeze/thaw cycles. Allow the paint to slowly warm up to room temperature, then stir it well. If the paint color and consistency appear normal, then it should be all right to use.
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